Ordained Priest | Years | Name | Current Title |
7 Apr 1963 |
| Archbishop Diego Causero | Apostolic Nuncio |
21 Sep 1963 |
| Bishop Armando Umberto Gianni, O.F.M. Cap. | Bishop Emeritus of Bouar |
21 Sep 1967 |
| Bishop Albert Vanbuel, S.D.B. | Bishop Emeritus of Kaga-Bandoro |
19 Mar 1970 |
| Bishop Guerrino Perin, M.C.C.I. | Bishop Emeritus of Mbaďki |
24 Mar 1974 |
| Archbishop Pierre Nguyễn Văn Tốt | Apostolic Nuncio |
13 Jul 1980 |
| Archbishop Paulin Pomodimo | Archbishop Emeritus of Bangui |
13 Sep 1980 |
| Bishop Juan-José Aguirre Muńoz, M.C.C.I. | Bishop of Bangassou |
12 Sep 1981 |
| Archbishop Franco Coppola | Apostolic Nuncio to Belgium |
2 Jul 1983 |
| Archbishop Jude Thaddeus Okolo | Apostolic Nuncio to Czech Republic |
22 Sep 1985 |
| Bishop François-Xavier Yombandje | Bishop Emeritus of Bossangoa |
27 Jul 1986 |
| Bishop Jean-Claude Rembanga | Bishop Emeritus of Bambari |
11 Jul 1987 |
| Bishop Jesús Ruiz Molina, M.C.C.I. | Bishop of Mbaďki |
12 Jun 1988 |
| Bishop Mirosław Gucwa | Bishop of Bouar |
27 May 1989 |
| Archbishop Santiago De Wit Guzmán | Apostolic Nuncio to Trinidad and Tobago, Antilles |
27 May 1989 |
| Bishop Aurelio Gazzera, O.C.D. | Coadjutor Bishop of Bangassou |
8 Aug 1992 |
| Bishop Victor Hugo Castillo Matarrita, M.C.C.I. | Bishop of Kaga-Bandoro |
12 Nov 1994 |
| Archbishop Giuseppe Laterza | Apostolic Nuncio to Central African Republic |
12 Jul 1997 |
| Bishop Dennis Kofi Agbenyadzi, S.M.A. | Bishop of Berbérati |
9 Aug 1998 |
| Dieudonné Cardinal Nzapalainga, C.S.Sp. | Archbishop of Bangui |
23 Aug 1998 |
| Bishop Nestor-Désiré Nongo-Aziagbia, S.M.A. | Bishop of Bossangoa |
18 Mar 2001 |
| Bishop Cyr-Nestor Yapaupa | Bishop of Alindao |
1 Nov 2004 |
| Bishop Bertrand Guy Richard Appora-Ngalanibé, O.P. | Bishop of Bambari |